首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   875篇
  免费   114篇
  国内免费   80篇
化学   313篇
晶体学   3篇
力学   49篇
综合类   3篇
数学   467篇
物理学   234篇
  2024年   1篇
  2023年   56篇
  2022年   42篇
  2021年   59篇
  2020年   75篇
  2019年   36篇
  2018年   37篇
  2017年   38篇
  2016年   43篇
  2015年   57篇
  2014年   80篇
  2013年   97篇
  2012年   101篇
  2011年   102篇
  2010年   96篇
  2009年   50篇
  2008年   35篇
  2007年   6篇
  2006年   5篇
  2005年   4篇
  2004年   6篇
  2003年   2篇
  2002年   4篇
  2001年   10篇
  2000年   8篇
  1999年   6篇
  1998年   7篇
  1997年   1篇
  1992年   1篇
  1990年   2篇
  1985年   1篇
  1936年   1篇
排序方式: 共有1069条查询结果,搜索用时 62 毫秒
1.
We define the notion of basic set data for finite groups (building on the notion of basic set, but including an order on the irreducible characters as part of the structure), and we prove that the Springer correspondence provides basic set data for Weyl groups. Then we use this to determine explicitly the modular Springer correspondence for classical types (defined over a base field of odd characteristic p, and with coefficients in a field of odd characteristic ?p): the modular case is obtained as a restriction of the ordinary case to a basic set. In order to do so, we compare the order on bipartitions introduced by Dipper and James with the order induced by the Springer correspondence. We provide a quick proof, by sorting characters according to the dimension of the corresponding Springer fibre, an invariant which is directly computable from symbols.  相似文献   
2.
High-throughput metabolic analysis is of significance in diagnostics, while tedious sample pretreatment has largely hindered its clinic application. Herein, we designed FeOOH@ZIF-8 composites with enhanced ionization efficiency and size-exclusion effect for laser desorption/ionization mass spectrometry (LDI-MS)-based metabolic diagnosis of gynecological cancers. The FeOOH@ZIF-8-assisted LDI-MS achieved rapid, sensitive, and selective metabolic fingerprints of the native serum without any enrichment or purification. Further analysis of extracted serum metabolic fingerprints successfully discriminated patients with gynecological cancers (GCs) from healthy controls and also differentiated three major subtypes of GCs. Given the low cost, high-throughput, and easy operation, our approach brings a new dimension to disease analysis and classification.  相似文献   
3.
4.
5.
To construct a class of new multiwave interaction solutions for the (3+1)-dimensional generalized Kadomtsev-Petviashvili equation, we calculate different types of interaction solutions among solitons, periodic waves and rational waves using the direct algebraic method together with the inheritance solving skill. Moreover, a new algorithm is proposed with the aid of the simplified Hirota method, the conjugated parameters assignment and long wave limit strategies, from which multiwave interaction solutions among solitons, breathers and lump waves are generated.  相似文献   
6.
DNAzymes are a promising class of bioinspired catalyst; however, their structural instability limits their potential. Herein, a method to stabilize DNAzymes by encapsulating them in a metal–organic framework (MOF) host is reported. This biomimetic mineralization process makes DNAzymes active under a wider range of conditions. The concept is demonstrated by encapsulating hemin-G-quadruplex (Hemin-G4) into zeolitic imidazolate framework-90 (ZIF-90), which indeed increases the DNAzyme's structural stability. The stabilized DNAzymes show activities in the presence of Exonuclease I, organic solvents, or high temperature. Owing to its elevated stability and heterogeneous nature, it is possible to perform catalysis under continuous-flow conditions, and the DNAzyme can be reactivated in situ by introducing K+. Moreover, it is found that the encapsulated DNAzyme maintains its high enantiomer selectivity, demonstrated by the sulfoxidation of thioanisole to (S)-methyl phenyl sulfoxide. This concept of stabilizing DNAzymes expands their potential application in chemical industry.  相似文献   
7.
We generalize the monomorphism category from quiver (with monomial relations) to arbitrary finite dimensional algebras by a homological definition. Given two finite dimension algebras A and B, we use the special monomorphism category Mon(B,A-Gproj) to describe some Gorenstein projective bimodules over the tensor product of A and B. If one of the two algebras is Gorenstein, we give a sufficient and necessary condition for Mon(B,A-Gproj) being the category of all Gorenstein projective bimodules. In addition, if both A and B are Gorenstein, we can describe the category of all Gorenstein projective bimodules via filtration categories. Similarly, in this case, we get the same result for infinitely generated Gorenstein projective bimodules.  相似文献   
8.
Lu  Xin 《Mathematische Zeitschrift》2019,291(3-4):1381-1387
Mathematische Zeitschrift - In this note, we construct non-isotrivial families of curves of genus $$g\ge 2$$ , where the rank of the unitary summand contained in the Hodge bundle can be as large as...  相似文献   
9.
We prove the existence of solutions to the nonlinear Schrödinger equation ε2(i?+A)2u+V(y)u?|u|p?1u=0 in R2 with a magnetic potential A=(A1,A2). Here V represents the electric potential, the index p is greater than 1. Along some sequence {εn} tending to zero we exhibit complex-value solutions that concentrate along some closed curves.  相似文献   
10.
As one of the biological endogenous pigments, biliverdin (BV) and its dimethyl ester (BVE) have extremely weak fluorescence in solution with quantum yield less than 0.01%. However, the situation reverses with the addition of zinc ions. The strength for fluorescence of BVE-Zn\begin{document}$ ^{2+} $\end{document} complex is greatly enhanced and fluorescence quantum yield can increase to \begin{document}$ \sim $\end{document}5%. Herein, we studied ultrafast excited state dynamics of BVE-Zn\begin{document}$ ^{2+} $\end{document} complex in ethanol, \begin{document}$ n $\end{document}-propanol, and DMSO solutions in order to reveal the mechanism of fluorescence quantum yield enhancement. The results show that BVE can form a stable coordination complex with zinc with 1:1 stoichiometry in solution. BVE is structurally and energetically more stable in the complex. Using picosecond time-resolve fluorescence and femtosecond transient absorption spectroscopy, we show that smaller non-radiative rate constant of BVE-Zn\begin{document}$ ^{2+} $\end{document} complex in DMSO is the key to increasing its fluorescence quantum yield and the excited state decay mechanism is also revealed. These results provide valuable information about the fluorescence property change after BVE binding to metal ions and may provide a guidance for the study of phytochromes or other fluorescence proteins in which BV/BVE acts as chromophores.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号